全文获取类型
收费全文 | 223篇 |
免费 | 0篇 |
国内免费 | 1篇 |
专业分类
化学 | 131篇 |
晶体学 | 1篇 |
力学 | 1篇 |
数学 | 11篇 |
物理学 | 80篇 |
出版年
2023年 | 4篇 |
2022年 | 2篇 |
2021年 | 4篇 |
2020年 | 7篇 |
2019年 | 1篇 |
2018年 | 1篇 |
2017年 | 1篇 |
2015年 | 5篇 |
2014年 | 6篇 |
2013年 | 10篇 |
2012年 | 11篇 |
2011年 | 16篇 |
2010年 | 7篇 |
2009年 | 13篇 |
2008年 | 15篇 |
2007年 | 19篇 |
2006年 | 18篇 |
2005年 | 20篇 |
2004年 | 20篇 |
2003年 | 11篇 |
2002年 | 9篇 |
2001年 | 9篇 |
2000年 | 11篇 |
1999年 | 2篇 |
1998年 | 2篇 |
排序方式: 共有224条查询结果,搜索用时 31 毫秒
11.
Noriyuki Kida Masanori Hikita Izuru Kashima Masaya Enomoto Miho Itoi Norimichi Kojima 《Polyhedron》2009,28(9-10):1694-1697
A photo-sensitive organic–inorganic hybrid system (SP)[FeIIFeIII(dto)3] (SP = spiropyran, dto = C2O2S2), has recently been developed, where the photo-isomerization of the intercalated spiropyran in solid state triggers the change of the magnetic properties, including the ferromagnetic transition temperature from 5 to 22 K. We performed 57Fe Mössbauer measurement in order to probe the microscopic states of iron ions in (SP)[FeIIFeIII(dto)3] and have investigated the photo-induced effect on them. The sample without UV-irradiation shows the charge transfer phase transition between 200 and 70 K and the higher and lower temperature phases coexist below 70 K, whereas the UV-irradiated sample does not undergo the charge transfer phase transition and the higher temperature phase is stable between 200 and 6 K. 相似文献
12.
-Ni(H2O)6 · SO4 and its selenate derivative exhibit chirality only in the solid-state. We have observed, for the first time, a sign inversion of CD (circular dichroism) in the 3A2g → 3T1g(P) Ni(II) d–d transition at near liquid nitrogen temperatures. The novel finding was achieved by building a new cooling unit to a solid-state specialized Universal Chiroptical Spectrophotometer (UCS-1) [R. Kuroda, T. Harada, Y. Shindo, Rev. Sci. Instrum. 72 (2001) 3802.] and by formulating an analytical procedure to obtain artifact-free CD signals based on the Mueller matrix method. The sign inversion is remarkable as the crystal structure hardly changes from 300 to 100 K. The origin of the sign inversion is discussed. 相似文献
13.
D. Moromachi A. Kuno M. Matsuo 《Journal of Radioanalytical and Nuclear Chemistry》2008,278(2):495-498
In order to investigate the transition of tidelands, we collected sediments in Yatsu tideland and Nekozane river mouth in Tokyo Bay. The vertical distributions of elements were determined by instrumental neutron activation analysis and prompt gamma-ray analysis. In Yatsu tideland the vertical distribution changed in a great extent, which was considered as an influence of the neighboring reclamation. They were categorized into four groups, and two parameters were created by applying principal component analysis. Chemical states of iron and sulfur were also investigated by Mössbauer spectroscopy and X-ray absorption fine structure. These results show that Yatsu tideland became an anaerobic environment. 相似文献
14.
15.
We propose a new gauge field theory which is an extension of ordinary string field theory by assembling multiple state spaces of the bosonic string. The theory includes higher-spin fields in its massless spectrum together with the infinite tower of massive fields. From the theory, we can easily extract the minimal gauge-invariant quadratic action for tensor fields with any symmetry. As examples, we explicitly derive the gauge-invariant actions for some simple mixed symmetric tensor fields. We also construct covariantly gauge-fixed action by extending the method developed for string field theory. 相似文献
16.
Yoshitane Imai Kensaku Kamon Nobuo Tajima Reiko Kuroda Yoshio Matsubara 《Tetrahedron》2007,63(48):11928-11932
Chiral charge-transfer (CT) complexes composed of a chiral 1,1′-bi-2-naphthol cluster as the electron donor and 1,1′-dibenzyl-4,4′-bipyridinium dichloride as the electron acceptor serve as a host system for molecular recognition. CT complexes that include guest alcohols show different diffuse reflectance spectra (DRS) depending on the included guest. 相似文献
17.
18.
[reaction: see text] The origin of exclusive exo-stereochemistry in the alkylation of Meyers-type enolate 2 has been studied. It was found that the intramolecular complex with a strong Li...O(ring) interaction (the O-complex) may be responsible as the major enolate species in tetrahydrofuran (THF). The transition state of the O-complex leading to exo-stereochemistry is found to be the most favorable process in THF. 相似文献
19.
Yoshitane Imai Kakuhiro Kawaguchi Tomohiro Sato Michiya Fujiki Yoshio Matsubara 《Tetrahedron letters》2007,48(16):2927-2930
By using (1R,2R)-1,2-diphenylethylenediamine as a chiral molecule and 2-anthracenecarboxylic acid as a fluorescent molecule, we created a chiral supramolecular organic fluorophore having circularly polarized luminescence properties in the solid-state. 相似文献
20.
For the expansion of a rectangular cavity (RC) defined by two isonicotinic acid (isoH) dimers as bridging ligands and two SCN bridges, we conducted a structural extension based on the elongation of the bridging ligands by the replacement of isoH with longer 4-pyridyl-substituted carboxylic acid (PCA). For this purpose, the following three PCAs have been employed: trans-3-(4-pyridyl)propenoic acid (acrylH), 4-(4-pyridyl)benzoic acid (pybenH), and trans-3-(4-(4-pyridyl)phenyl)propenoic acid (pppeH). Self-assembly of Ni2+, SCN-, and each of four PCAs involving isoH, acrylH, pybenH, and pppeH in the presence of an aromatic guest gave four inclusion compounds formulated as [Ni(SCN)2(isoH)2].1/2(benz[a]anthracene) (1), [Ni(SCN)2(acrylH)2].1/2(benz[a]anthracene) (2), [Ni(SCN)2(pybenH)2].(pyrene) (3), and [Ni(SCN)2(pppeH)2](3/)(2).(benz[a]anthracene) (4). X-ray crystal structural determination of 1-4 revealed that the proposed structural extension was successful. Their crystal structures are layered structures of two-dimensional (2D) grid-type coordination frameworks (2D host layers) framed with bridging ligands of the corresponding PCA dimers and 1D chains consisting of Ni2+ ions and mu(1,3)-SCN- ions. The lengths of the PCA dimers are 12.269(5) A (isoH dimer), 16.890(4) A (acrylH dimer), 20.89(2) A (pybenH dimer), 25.387(3) A (pppeH dimer A), and 25.527(4) A (pppeH dimer B). Each 2D host layer has RCs defined by the two corresponding PCA dimers and the two SCN bridges. The dimensions of RCs are expanded in proportion to the increase in the lengths of the PCA dimers: 29.52 x 5.60-7.20 A2 (4) > 24.95 x 5.46-7.38 A2 (3) > 20.88 x 5.49-7.25 A2 (2) > 16.41 x 5.53-7.43 A2 (1). These expansions reflect the number of aromatic guests that can be included in RCs. RC of 1 include only one molecule of benz[a]anthracene, whereas RCs of 3 or 4 includes two molecules of pyrene or benz[a]anthracene, respectively. Comparison of the lengths between the PCA dimers and 4,4'-bipyridine-type ligands demonstrated that a design strategy-the preparation of a bridging ligand through self-assembly of two PCAs-is both efficient and particularly suitable for the preparation of very long bridging ligands. 相似文献